unimolecular reaction

The mechanisms of the hydrolysis were proposed to be unimolecular nucleophilic substitution and bimolecular nucleophilic substitution ( SN2). On the Problem of Bimolecular Nucleophilic Substitution Reaction Sterochemistry

水解反应的可能机理是S Nl和S N2.双分子亲核取代反应立体化学问题释疑

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The unimolecular decomposition and dehydrogenation of ethanol initiate the branched chain reaction, and the3 isomers of radical C2H5O determine the direction of the reaction chain branching.

乙醇氧化经裂解反应、脱氢反应最终形成支链反应，乙氧基C2H5O的三种同分异构体在链分支中决定了链分支的进行方向。

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Kinetics of unimolecular reaction of cf_2hcl on W surface

CF2HCI在金属钨表面上的反应动力学

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The results obtained show that these compounds undergo unimolecular first-order pyrolytic reaction via a six-center cyclic transition state. This kind of the reaction is controlled by migrating of the atom H 17 with positive charge.

结果表明反应是一个H17带正电迁移引发的途经六元环过渡态的单分子热消除反应。

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In the reaction mechanism of unimolecular nucleophilic substitution ( SN1), it can produce carbocations which can easily lead to the racemization of the products.

由于单分子亲核取代反应（SN1）经过了碳正离子中间体的历程，所以得到的产物是外消旋的。

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A Computer Program for Tunneling in Unimolecular Thermal Reaction System in Chemical Kinetics-KANDE

化学动力学中单分子热反应隧道效应计算程序KANDE

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